Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 37, 2009
Previous Article Next Article

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

Author affiliations

Abstract

Iridium trisboryl complexes containing bisphosphine and bipyridine ligands and pinacolate and catecholate substituents on boron are reported. A large difference in reactivity towards the borylation of C–H bonds is observed for this series of trisboryl complexes, and this difference is attributed to the electron-donating properties of the pinacolate vs.catecholate groups, and the steric and electronic properties of bipyridinevs.bisphosphine ligands.

Graphical abstract: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

Back to tab navigation

Supplementary files

Additions and corrections

Article information


Submitted
14 Jul 2009
Accepted
07 Aug 2009
First published
20 Aug 2009

Chem. Commun., 2009, 5603-5605
Article type
Communication

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

C. W. Liskey, C. S. Wei, D. R. Pahls and J. F. Hartwig, Chem. Commun., 2009, 5603
DOI: 10.1039/B913949D

Social activity

Search articles by author

Spotlight

Advertisements