Green molecular transformation by a B12–TiO2 hybrid catalyst as an alternative to tributyltin hydride

Hisashi Shimakoshi; Makoto Abiru; Shin-ichiro Izumi; Yoshio Hisaeda

doi:10.1039/B913255D

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Green molecular transformation by a B₁₂–TiO₂ hybrid catalyst as an alternative to tributyltin hydride†

Hisashi Shimakoshi,^a Makoto Abiru,^a Shin-ichiro Izumi^a and Yoshio Hisaeda*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan
E-mail: yhisatcm@mail.cstm.kyushu-u.ac.jp
Fax: +81-92-802-2827

Abstract

The B₁₂–TiO₂ hybrid catalyst was effectively used for the radical reactions, such as 1,2-migrations of phenyl groups and acyl groups under irradiation by UV light, and the selectivity of the reaction was controlled by the solvent system.

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Supplementary files

Details of experimental procedures PDF (255K)

Article information

DOI: https://doi.org/10.1039/B913255D
Article type: Communication
Submitted: 03 Jul 2009
Accepted: 18 Aug 2009
First published: 09 Sep 2009

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Chem. Commun., 2009, 6427-6429

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Green molecular transformation by a B₁₂–TiO₂ hybrid catalyst as an alternative to tributyltin hydride

H. Shimakoshi, M. Abiru, S. Izumi and Y. Hisaeda, Chem. Commun., 2009, 6427 DOI: 10.1039/B913255D

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Chemical Communications