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Issue 37, 2009
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Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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Abstract

Lewis bases, including reactant aldehydes, inhibit the rate of conversion for cycloaddition and those, like aldehydes or nitriles, cause a decrease in enantiocontrol due to the Lewis acidity of the activated complex.

Graphical abstract: Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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Article information


Submitted
01 Jul 2009
Accepted
14 Aug 2009
First published
26 Aug 2009

Chem. Commun., 2009, 5612-5614
Article type
Communication

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

X. Wang, Z. Li and M. P. Doyle, Chem. Commun., 2009, 5612
DOI: 10.1039/B913019E

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