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Issue 45, 2009
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Solid-phase synthesis of protected α-amino phosphonic acid oligomers

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Abstract

By establishing both a highly efficient phosphonamidate formation and a RuCp-catalyzed cleavage of an allyl linker, the solid-phase synthesis of Fmoc-(GlyP(OBn))6-OH/DIEA, a protected form of a new type of unnatural peptide α-amino phosphonic acid oligomer (APO), has been realized.

Graphical abstract: Solid-phase synthesis of protected α-amino phosphonic acid oligomers

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Publication details

The article was received on 22 Jun 2009, accepted on 30 Sep 2009 and first published on 14 Oct 2009


Article type: Communication
DOI: 10.1039/B912231A
Citation: Chem. Commun., 2009,0, 6985-6987
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    Solid-phase synthesis of protected α-amino phosphonic acid oligomers

    Y. Ishibashi and M. Kitamura, Chem. Commun., 2009, 0, 6985
    DOI: 10.1039/B912231A

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