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Issue 33, 2009
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Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions

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Abstract

8-Hydroxy-6-methyl-5,6,7,8-tetrahydroimidazo[1,2-a]pyridine was formed selectively in high yields from N-(β-methallyl)imidazole by a tandem hydroformylation–cyclization sequence, representing a novel one-pot catalytic synthesis of bicyclic imidazole derivatives.

Graphical abstract: Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions

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Publication details

The article was received on 12 Jun 2009, accepted on 07 Jul 2009 and first published on 23 Jul 2009


Article type: Communication
DOI: 10.1039/B911612E
Citation: Chem. Commun., 2009,0, 4944-4946
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    Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions

    P. S. Bäuerlein, I. A. Gonzalez, J. J. M. Weemers, M. Lutz, A. L. Spek, D. Vogt and C. Müller, Chem. Commun., 2009, 0, 4944
    DOI: 10.1039/B911612E

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