An endohedral titanium(III) in a clusterfullerene: putting a non-group-III metal nitride into the C80-Ihfullerene cage

Shangfeng Yang; Chuanbao Chen; Alexey A. Popov; Wenfeng Zhang; Fupin Liu; Lothar Dunsch

doi:10.1039/B911267G

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An endohedral titanium(iii) in a clusterfullerene: putting a non-group-III metal nitride into the C₈₀-I_hfullerene cage†

Shangfeng Yang,*^a Chuanbao Chen,^a Alexey A. Popov,^b Wenfeng Zhang,^a Fupin Liu^a and Lothar Dunsch^b

Author affiliations

* Corresponding authors

^a Hefei National Laboratory for Physical Sciences at Microscale & Department of Materials Science and Engineering, University of Science and Technology of China (USTC), Hefei 230026, China
E-mail: sfyang@ustc.edu.cn
Fax: +86(551)3601 750
Tel: +86(551)3601 750

^b Group of Electrochemistry and Conducting Polymers, Leibniz-Institute for Solid State and Materials Research (IFW) Dresden, D-01171 Dresden, Germany

Abstract

With the successful isolation of TiSc₂N@C₈₀, the first Ti-containing nitride clusterfullerene (NCF), a non-group-III metal is stabilized in a NCF for the first time.

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Supplementary files

Synthesis and detailed isolation of TiSc₂N@C₈₀, estimation of the relative yield of TiSc₂N@C₈₀ to those of Sc₃N@C₈₀ (I) and Sc₃N@C₈₀ (II) etc. PDF (945K)

Article information

DOI: https://doi.org/10.1039/B911267G
Article type: Communication
Submitted: 09 Jun 2009
Accepted: 08 Sep 2009
First published: 24 Sep 2009

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Chem. Commun., 2009, 6391-6393

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An endohedral titanium(III) in a clusterfullerene: putting a non-group-III metal nitride into the C₈₀-I_hfullerene cage

S. Yang, C. Chen, A. A. Popov, W. Zhang, F. Liu and L. Dunsch, Chem. Commun., 2009, 6391 DOI: 10.1039/B911267G

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