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Issue 38, 2009
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The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

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Abstract

New C2-symmetric tetrafluorobenzobarrelene ligands were prepared and applied successfully to the rhodium-catalyzed asymmetric addition of arylboronic acids to aromaticaldehydes giving chiral diarylmethanols in high yield with high enantioselectivity.

Graphical abstract: The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

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Publication details

The article was received on 05 Jun 2009, accepted on 27 Jul 2009 and first published on 17 Aug 2009


Article type: Communication
DOI: 10.1039/B911118B
Citation: Chem. Commun., 2009,0, 5713-5715
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    The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

    T. Nishimura, H. Kumamoto, M. Nagaosa and T. Hayashi, Chem. Commun., 2009, 0, 5713
    DOI: 10.1039/B911118B

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