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Issue 43, 2009
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A tetranuclear iridium(iii) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage

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Abstract

A novel tetranuclear Ir(III) complex involving unprecedented coordination modes of alloxazine formed a closed π-space by intermolecular hydrogen bonding and the counter anions encapsulated in the space could be exchanged viaself-assembly.

Graphical abstract: A tetranuclear iridium(iii) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage

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Article information


Submitted
04 Jun 2009
Accepted
09 Sep 2009
First published
25 Sep 2009

Chem. Commun., 2009, 6643-6645
Article type
Communication

A tetranuclear iridium(III) complex with a flavin analogue as a bridging ligand in different coordination modes and exchangeable anion encapsulation in a supramolecular cage

T. Kojima, Y. Inui, S. Miyazaki, M. Shiro and S. Fukuzumi, Chem. Commun., 2009, 6643
DOI: 10.1039/B911033J

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