Issue 21, 2009
From the journal:

Chemical Communications

Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents†

Carolynne Ricardoa  and  Tomislav Pintauer*a  

* Corresponding authors

a Duquesne University, Department of Chemistry and Biochemistry, 600 Forbes Avenue, 308 Mellon Hall, Pittsburgh, USA
E-mail: pintauert@duq.edu
Fax: +1 412-396-5683
Tel: +1 412-396-1626

Abstract

Exceptional activity of [CuII(TPMA)Cl][Cl] (TPMA = tris(2-pyridylmethyl)amine) complex in atom transfer radical addition (ATRA) of CCl4 to 1,6-dienes followed by sequential atom transfer radical cyclization (ATRC) in the presence of free-radical diazo initiators as reducing agents is reported.

Graphical abstract: Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

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Article information

DOI
https://doi.org/10.1039/B905839G
Article type
Communication
Submitted
24 Mar 2009
Accepted
18 Apr 2009
First published
05 May 2009

Chem. Commun., 2009, 3029-3031

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Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

C. Ricardo and T. Pintauer, Chem. Commun., 2009, 3029 DOI: 10.1039/B905839G

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