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Issue 32, 2009
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Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

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Abstract

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.

Graphical abstract: Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

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Publication details

The article was received on 06 Mar 2009, accepted on 24 Apr 2009 and first published on 19 May 2009


Article type: Communication
DOI: 10.1039/B904624K
Citation: Chem. Commun., 2009,0, 4815-4817

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    Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

    K. Okamoto, T. Hayashi and V. H. Rawal, Chem. Commun., 2009, 0, 4815
    DOI: 10.1039/B904624K

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