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Abstract | Cited by

Polymerization-induced formation of amphiphilic diblock copolymer vesicles is performed in water at high concentrations by a single-step nitroxide-mediated controlled free-radical emulsion polymerization of 4-vinylpyridine, initiated by a water-soluble poly(sodium acrylate) macroalkoxyamine at alkaline pH.

Graphical abstract: Formation of polymer vesicles by simultaneous chain growth and self-assembly of amphiphilic block copolymers

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