Issue 20, 2009
From the journal:

Chemical Communications

Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile†

Li-Rong Guo,a   Song-Song Bao,a   Yi-Zhi Lia  and  Li-Min Zheng*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China
E-mail: lmzheng@nju.edu.cn
Fax: (+) 86-25-83314502

Abstract

A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO3 in CH3CN under solvothermal conditions; the process is coupled with the C–C bond cleavage of acetonitrile and the formation of novel complexes [Agn(RPO2(O)O2PR)m](CN); the mechanism of the process is proposed.

Graphical abstract: Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

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Article information

DOI
https://doi.org/10.1039/B902162K
Article type
Communication
Submitted
02 Feb 2009
Accepted
16 Mar 2009
First published
06 Apr 2009

Chem. Commun., 2009, 2893-2895

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Ag(I)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

L. Guo, S. Bao, Y. Li and L. Zheng, Chem. Commun., 2009, 2893 DOI: 10.1039/B902162K

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