Issue 18, 2009
From the journal:

Chemical Communications

An unexpected bonding interaction between dxy and axial cyanide mediated by porphyrin deformation

Ru-Jen Cheng,*a   Chang-Hung Leea  and  Chia-Wei Chaoa  

* Corresponding authors

a Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan, Republic of China
E-mail: rjcheng@mail.nchu.edu.tw
Fax: +886-4-22862547
Tel: +886-4-22871190

Abstract

Through density functional calculation and NMR spectroscopy, an unexpected bonding interaction between dxy and axial cyanides is revealed to account for the lower shielding of axial cyanide of ruffled [Fe(TRP)(CN)2]− complexes with the contribution of the unusual low-spin electronic structure (dxzdyz)4(dxy)1.

Graphical abstract: An unexpected bonding interaction between dxy and axial cyanide mediated by porphyrin deformation

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B901116A
Article type
Communication
Submitted
19 Jan 2009
Accepted
24 Feb 2009
First published
23 Mar 2009

Chem. Commun., 2009, 2526-2528

Permissions

Request permissions

An unexpected bonding interaction between dxy and axial cyanide mediated by porphyrin deformation

R. Cheng, C. Lee and C. Chao, Chem. Commun., 2009, 2526 DOI: 10.1039/B901116A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements