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Hexaazido and hexaiodo macrocyclic methanofullerenes undergo high-yielding sixfold click reactions or sixfold Heck, Sonogashira and Suzuki cross-coupling reactions, respectively, to yield all organic building blocks for higher molecular architectures.

Graphical abstract: Functionalization of hexakis methanofullerene malonate crown-ethers: promising octahedral building blocks for molecular networks

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