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Issue 14, 2009
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Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium

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Abstract

An organoindium generated from the reaction of indium with allenylmethyl bromide is an efficient nucleophile in Pd-catalyzed cross-couplings, producing 1,3-butadienes; cross-couplings followed by [4 + 2] cycloadditions gave six-membered carbocycles in a one-pot process.

Graphical abstract: Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium

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Article information


Submitted
22 Dec 2008
Accepted
23 Jan 2009
First published
23 Feb 2009

Chem. Commun., 2009, 1873-1875
Article type
Communication

Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium

S. Kim, D. Seomoon and P. H. Lee, Chem. Commun., 2009, 1873
DOI: 10.1039/B823037D

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