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Issue 13, 2009
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C–H oxidation by hydroxo manganese(V) porphyrins: a DFT study

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Abstract

A DFT study on toluene oxidation by Mn(V) porphyrins shows that both MnV(O) and, remarkably, MnV(OH) are potent H-atom abstractors.

Graphical abstract: C–H oxidation by hydroxo manganese(v) porphyrins: a DFT study

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Publication details

The article was received on 25 Nov 2008, accepted on 29 Jan 2009 and first published on 17 Feb 2009


Article type: Communication
DOI: 10.1039/B821029B
Citation: Chem. Commun., 2009,0, 1772-1774

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    C–H oxidation by hydroxo manganese(V) porphyrins: a DFT study

    D. Balcells, C. Raynaud, R. H. Crabtree and O. Eisenstein, Chem. Commun., 2009, 0, 1772
    DOI: 10.1039/B821029B

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