Issue 12, 2009
From the journal:

Chemical Communications

Activation of hydrocarbon C–H bonds by iodosylbenzene: how does it compare with iron(iv)–oxo oxidants?†

Soo Jeong Kim,a   Reza Latifi,bc   Hye Yeon Kang,a   Wonwoo Nam*a  and  Sam P. de Visser*b  

* Corresponding authors

a Department of Chemistry and Nano Science and Department of Bioinspired Science, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 2 3277 4441
Tel: +82 2 3277 2392

b The Manchester Interdisciplinary Biocenter and the School of Chemical Engineering and Analytical Science, 131 Princess Street, Manchester, UK
E-mail: sam.devisser@manchester.ac.uk
Fax: +44 161 3065201
Tel: +44 161 3064882

c Chemistry Department, Sharif University of Technology, PO Box 11155-3615, Tehran, Iran

Abstract

Combined experimental and theoretical studies on the reactivity of iodosylbenzene (PhIO) show that PhIO is capable of activating weak C–H bonds of hydrocarbonsvia a hydrogen abstraction mechanism.

Graphical abstract: Activation of hydrocarbon C–H bonds by iodosylbenzene: how does it compare with iron(iv)–oxo oxidants?

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Article information

DOI
https://doi.org/10.1039/B820812C
Article type
Communication
Submitted
20 Nov 2008
Accepted
05 Jan 2009
First published
03 Feb 2009

Chem. Commun., 2009, 1562-1564

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Activation of hydrocarbon C–H bonds by iodosylbenzene: how does it compare with iron(IV)–oxo oxidants?

S. J. Kim, R. Latifi, H. Y. Kang, W. Nam and S. P. de Visser, Chem. Commun., 2009, 1562 DOI: 10.1039/B820812C

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