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Issue 13, 2009
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A small cationic donor–acceptor iridium complex with a long-lived charge-separated state

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Abstract

A cationic cyclometalated iridium complex with a triarylamine donor attached to the primary ligand sphere showed long-lived (0.04 and 1.7 μs) charge-separated states after photoexcitation which are due to a combined Marcus inverted region effect and spin-selection rules.

Graphical abstract: A small cationic donor–acceptor iridium complex with a long-lived charge-separated state

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Publication details

The article was received on 20 Nov 2008, accepted on 23 Jan 2009 and first published on 11 Feb 2009


Article type: Communication
DOI: 10.1039/B820744E
Chem. Commun., 2009, 1670-1672

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    A small cationic donor–acceptor iridium complex with a long-lived charge-separated state

    B. Geiß and C. Lambert, Chem. Commun., 2009, 1670
    DOI: 10.1039/B820744E

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