Abstract
The synthesis of [NpVIO2Cl2(thf)]n offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex [{NpVIO2Cl2}{NpVO2Cl(thf)3}2] allows molecular neptunyl(V) ‘
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* Corresponding authors
a Centre for Radiochemistry Research, School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
b
Department of Chemistry, University College London, 20 Gordon Street, London, UK
E-mail:
n.kaltsoyannis@ucl.ac.uk
Fax: +44 (0)2076 796463
Tel: +44(0)2076 794670
c The UK National Nuclear Laboratory, Central Laboratory, Sellafield, Seascale, Cumbria, UK
d School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
e
Chemistry – Inorganic, Isotope and Actinide Chemistry (C-IIAC), Los Alamos National Laboratory, Mail Stop J-514, Los Alamos, USA
E-mail:
iainmay@lanl.gov
Fax: +1(0)505 667 9905
Tel: +1(0)505 667 8643
The synthesis of [NpVIO2Cl2(thf)]n offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex [{NpVIO2Cl2}{NpVO2Cl(thf)3}2] allows molecular neptunyl(V) ‘
S. M. Cornet, L. J. L. Häller, M. J. Sarsfield, D. Collison, M. Helliwell, I. May and N. Kaltsoyannis, Chem. Commun., 2009, 917 DOI: 10.1039/B818973K
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