Issue 5, 2009

Iron-catalysed Negishi coupling of benzylhalides and phosphates

Abstract

Iron-based catalysts containing either 1,2-bis(diphenylphosphino)benzene or 1,3-bis(diphenylphosphino)propane give excellent activity and good selectivity in the Negishi coupling of aryl zinc reagents with a range of benzylhalides and phosphates.

Graphical abstract: Iron-catalysed Negishi coupling of benzylhalides and phosphates

Supplementary files

Article information

Article type
Communication
Submitted
27 Oct 2008
Accepted
19 Nov 2008
First published
11 Dec 2008

Chem. Commun., 2009, 600-602

Iron-catalysed Negishi coupling of benzylhalides and phosphates

R. B. Bedford, M. Huwe and M. C. Wilkinson, Chem. Commun., 2009, 600 DOI: 10.1039/B818961G

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