Issue 9, 2009
From the journal:

Chemical Communications

Enantiopure imidazolinium-dithiocarboxylates as highly selective novel organocatalysts†

Oksana Sereda,a   Amélie Blanruea  and  René Wilhelm*a  

* Corresponding authors

a Institute of Organic Chemistry, Clausthal University of Technology, Leibnizstr. 6, 38678 Clausthal-Zellerfeld, Germany
E-mail: rene.wilhelm@tu-clausthal.de
Fax: +49 (0)5323 722834
Tel: +49 (0)5323 723886

Abstract

Asymmetric imidazolinium-dithiocarboxylates have been found for the first time to be highly selective catalysts; in the present case, the novel organocatalysts were able to catalyze the Staudinger reaction in up to 96% ee and 99% yield.

Graphical abstract: Enantiopure imidazolinium-dithiocarboxylates as highly selective novel organocatalysts

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Article information

DOI
https://doi.org/10.1039/B817991C
Article type
Communication
Submitted
14 Oct 2008
Accepted
04 Dec 2008
First published
24 Dec 2008

Chem. Commun., 2009, 1040-1042

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Enantiopure imidazolinium-dithiocarboxylates as highly selective novel organocatalysts

O. Sereda, A. Blanrue and R. Wilhelm, Chem. Commun., 2009, 1040 DOI: 10.1039/B817991C

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