Issue 5, 2009
From the journal:

Chemical Communications

Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives†

Mike Joachim Zöllner,a   Ullrich Jahn,b   Eike Becker,a   Wolfgang Kowalskya  and  Hans-Hermann Johannes*a  

* Corresponding authors

a Labor für Elektrooptik am Institut für Hochfrequenztechnik, Technische Universität Braunschweig, Postfach 3329, Braunschweig, Germany
E-mail: h2.johannes@tu-bs.de
Fax: +49-531-391-8004
Tel: +49-531-391-2006

b Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo Namesti 2, Prague, Czech Republic

Abstract

Kinetically controlled lithiation of 3-hexoxythiophene in the 5-position allows the synthesis of interesting functionalised building blocks after reaction with N,N-dimethylformamide and iodine.

Graphical abstract: Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives

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Article information

DOI
https://doi.org/10.1039/B817089D
Article type
Communication
Submitted
29 Sep 2008
Accepted
03 Nov 2008
First published
02 Dec 2008

Chem. Commun., 2009, 565-567

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Simplified methods for the functionalisation of 3-hexoxythiophenes at the 5-position and further reactions to alkynyl and vinyl derivatives

M. J. Zöllner, U. Jahn, E. Becker, W. Kowalsky and H. Johannes, Chem. Commun., 2009, 565 DOI: 10.1039/B817089D

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