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Issue 7, 2009
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Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair

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Abstract

Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2-diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to their ionic nature.

Graphical abstract: Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair

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Publication details

The article was received on 29 Sep 2008, accepted on 12 Nov 2008 and first published on 15 Dec 2008


Article type: Communication
DOI: 10.1039/B817046K
Chem. Commun., 2009, 830-832

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    Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair

    D. Schmid, S. Loscher, D. Gudat, D. Bubrin, I. Hartenbach, T. Schleid, Z. Benkő and L. Nyulászi, Chem. Commun., 2009, 830
    DOI: 10.1039/B817046K

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