Issue 3, 2009
From the journal:

Chemical Communications

Topotactic intercalation of a bulky organic anion (thiacalix[4]arene) into LDH through an osmotic swelling/restoration reaction in formamide†

Gailing Huang,a   Shulan Ma,a   Xinhua Zhao,a   Xiaojing Yang*a  and  Kenta Ooib  

* Corresponding authors

a College of Chemistry, Beijing Normal University, Beijing 100875, China
E-mail: yang.xiaojing@bnu.edu.cn
Fax: +86 10 5880 2075
Tel: 86 10 5880 2960

b National Institute of Advanced Industrial Science and Technology, 2217-14 Hayashi, Takamatsu 761-0395, Japan
E-mail: k-ooi@aist.go.jp
Fax: +81 87 869 3554
Tel: +81 87 869 3511

Abstract

Utilizing the osmotic swelling of LDH in formamide, for the first time, the bulky thiacalix[4]arene anion is introduced, leading to the recovery of LDH layers, and the hexagonal prism morphology of the precursor is well retained.

Graphical abstract: Topotactic intercalation of a bulky organic anion (thiacalix[4]arene) into LDH through an osmotic swelling/restoration reaction in formamide

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Article information

DOI
https://doi.org/10.1039/B816996A
Article type
Communication
Submitted
30 Sep 2008
Accepted
11 Nov 2008
First published
25 Nov 2008

Chem. Commun., 2009, 331-333

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Topotactic intercalation of a bulky organic anion (thiacalix[4]arene) into LDH through an osmotic swelling/restoration reaction in formamide

G. Huang, S. Ma, X. Zhao, X. Yang and K. Ooi, Chem. Commun., 2009, 331 DOI: 10.1039/B816996A

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