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Issue 9, 2009
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Enclathration by a xanthenol hostvia solid–solid reactions: structures and kinetics

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Abstract

The host compound 9-(4-methoxyphenyl)-9H-xanthen-9-ol (H) forms inclusion compounds with the solid guests 1-naphthylamine, 8-hydroxyquinoline, triethylenediamine and acridine. All four structures were successfully solved in the triclinic spacegroup P[1 with combining macron]. Similar packing motifs arise for the 1-naphthylamine and the 8-hydroxyquinoline inclusion compounds where the main interaction is of the form (host)–OH⋯O–(host). Both the triethylenediamine and the acridine guests hydrogen bond to the host molecule. The thermal stabilities and kinetics of the solid–solid reactions were determined.

Graphical abstract: Enclathration by a xanthenol hostvia solid–solid reactions: structures and kinetics

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Article information


Submitted
02 Apr 2009
Accepted
18 Jun 2009
First published
14 Jul 2009

New J. Chem., 2009,33, 1960-1964
Article type
Paper

Enclathration by a xanthenol hostvia solid–solid reactions: structures and kinetics

A. Jacobs, L. R. Nassimbeni, K. L. Nohako, G. Ramon and J. H. Taljaard, New J. Chem., 2009, 33, 1960
DOI: 10.1039/B906720E

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