Jump to main content
Jump to site search

Volume 140, 2009
Previous Article Next Article

Steady state oxygenreduction and cyclic voltammetry

Author affiliations


The catalytic activity of Pt and Pt3Ni for the oxygen reduction reaction is investigated by applying a Sabatier model based on density functional calculations. We investigate the role of adsorbed OH on the activity, by comparing cyclic voltammetry obtained from theory with previously published experimental results with and without molecular oxygen present. We find that the simple Sabatier model predicts both the potential dependence of the OH coverage and the measured current densities seen in experiments, and that it offers an understanding of the oxygen reduction reaction (ORR) at the atomic level. To investigate kinetic effects we develop a simple kinetic model for ORR. Whereas kinetic corrections only matter close to the volcano top, an interesting outcome of the kinetic model is a first order dependence on the oxygen pressure. Importantly, the conclusion obtained from the simple Sabatier model still persists: an intermediate binding of OH corresponds to the highest catalytic activity, i.e. Pt is limited by a too strong OH binding and Pt3Ni is limited by a too weak OH binding.

Back to tab navigation

Publication details

The article was received on 06 Feb 2008, accepted on 28 Mar 2008 and first published on 20 Aug 2008

Article type: Paper
DOI: 10.1039/B802129E
Faraday Discuss., 2009,140, 337-346

  •   Request permissions

    Steady state oxygen reduction and cyclic voltammetry

    J. Rossmeisl, G. S. Karlberg, T. Jaramillo and J. K. Nørskov, Faraday Discuss., 2009, 140, 337
    DOI: 10.1039/B802129E

Search articles by author