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Issue 23, 2009
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A [Cu16S10]4−cluster containing μ3- and μ4-sulfido ligands

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Abstract

An anionic, “naked” copper sulfide cluster, [Cu16S10]4−, was synthesized by treating multi-copper starting materials with the hydrosulfide salt, (nBu4N)SH. The sixteen copper atoms in [Cu16S10]4− are arranged in a square gyrobicupola with eight μ3- and two μ4-sulfido ligands.

Graphical abstract: A [Cu16S10]4−cluster containing μ3- and μ4-sulfido ligands

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Article information


Submitted
19 Mar 2009
Accepted
02 Apr 2009
First published
20 Apr 2009

Dalton Trans., 2009, 4439-4441
Article type
Communication

A [Cu16S10]4−cluster containing μ3- and μ4-sulfido ligands

L. Yang, Z. Wang, D. R. Powell and R. P. Houser, Dalton Trans., 2009, 4439
DOI: 10.1039/B905375A

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