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Issue 32, 2009
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Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

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Abstract

The combination of a [1111] metacyclophane blocked in 1,3-alternate conformation and bearing four pyrazolyl coordinating units with MX2 (M = Co, Zn and X = Cl or Br) leads to the formation of crystals formed by packing of 2D coordination networks. In the case of CuBr2, the formation of a 1D network was observed. Structural studies by X-ray diffraction methods on single crystals were performed on all cases reported.

Graphical abstract: Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

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Publication details

The article was received on 23 Feb 2009, accepted on 19 May 2009 and first published on 29 Jun 2009


Article type: Paper
DOI: 10.1039/B903674A
Dalton Trans., 2009, 6309-6314

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    Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

    J. Ehrhart, J. Planeix, N. Kyritsakas-Gruber and M. W. Hosseini, Dalton Trans., 2009, 6309
    DOI: 10.1039/B903674A

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