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Issue 32, 2009
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Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

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Abstract

The combination of a [1111] metacyclophane blocked in 1,3-alternate conformation and bearing four pyrazolyl coordinating units with MX2 (M = Co, Zn and X = Cl or Br) leads to the formation of crystals formed by packing of 2D coordination networks. In the case of CuBr2, the formation of a 1D network was observed. Structural studies by X-ray diffraction methods on single crystals were performed on all cases reported.

Graphical abstract: Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

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Article information


Submitted
23 Feb 2009
Accepted
19 May 2009
First published
29 Jun 2009

Dalton Trans., 2009, 6309-6314
Article type
Paper

Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations

J. Ehrhart, J. Planeix, N. Kyritsakas-Gruber and M. W. Hosseini, Dalton Trans., 2009, 6309
DOI: 10.1039/B903674A

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