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Issue 14, 2009
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Synthesis and structural studies of metallamacrotricycles based on a metacyclophane in 1,3-alternate conformation bearing four imidazolyl units

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Abstract

The combination of a [1111]metacyclophane blocked in 1,3-alternate conformation and bearing four imidazole units with MX2 (M = Co, Cu, Zn and Hg; X = Cl or Br) complexes leads to the formation of a series of analogous neutral metallamacrotricycles. In all cases, the structure of the binuclear complexes has been studied by X-ray diffraction methods on single crystals.

Graphical abstract: Synthesis and structural studies of metallamacrotricycles based on a metacyclophane in 1,3-alternate conformation bearing four imidazolyl units

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Publication details

The article was received on 15 Sep 2008, accepted on 21 Jan 2009 and first published on 12 Feb 2009


Article type: Paper
DOI: 10.1039/B816053H
Dalton Trans., 2009, 2552-2557

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    Synthesis and structural studies of metallamacrotricycles based on a metacyclophane in 1,3-alternate conformation bearing four imidazolyl units

    J. Ehrhart, J. Planeix, N. Kyritsakas-Gruber and M. W. Hosseini, Dalton Trans., 2009, 2552
    DOI: 10.1039/B816053H

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