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Issue 40, 2009
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Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors

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Abstract

This paper reports the first systematical synthesis of near-monodisperse potassium and lithium rare earth (RE) fluoride (K(Li)REF4) nanocrystals with diverse shapes (cubic KLaF4 and KCeF4 wormlike nanowires, nanocubes and nanopolyhedra; cubic LiREF4 (RE = Pr to Gd, Y) nanopolyhedra; tetragonal LiREF4 (RE = Tb to Lu, Y) rhombic nanoplates) via co-thermolysis of Li(CF3COO) or K(CF3COO) and RE(CF3COO)3 in a hot oleic acid/oleylamine/1-octadecene solution. The effects of the solvent composition, reaction temperature and time on the crystal phase purity, shape, and size of the as-prepared nanocrystals have been investigated in detail. The formation of monodisperse nanocrystals is found to strongly depend upon the nature of both alkali metals from Li to K, and the rare earth series from La to Lu and Y. Based on the series of experimental results, a controlled-growth mechanism has also been proposed. In addition, the ease of doping of these as-synthesized host nanocrystals for designed luminescence properties is assessed. For example, monodisperse and single-crystalline Eu3+ doped KGdF4, Yb3+ and Er3+ co-doped LiYF4 nanocrystals redispersed in cyclohexane exhibit visible room-temperature red and green emissions under ultraviolet (UV) excitation and near infrared (NIR) 980 nm laser excitation, respectively.

Graphical abstract: Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors

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Publication details

The article was received on 08 May 2009, accepted on 21 Jul 2009 and first published on 02 Sep 2009


Article type: Paper
DOI: 10.1039/B909145A
Dalton Trans., 2009, 8574-8581

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    Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors

    Y. Du, Y. Zhang, L. Sun and C. Yan, Dalton Trans., 2009, 8574
    DOI: 10.1039/B909145A

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