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Issue 12, 2009
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Characterization of silica-supported dodecatungstic heteropolyacids as a function of their dehydroxylation temperature

Nicolas Legagneux,a   Jean-Marie Basset,a   Amélie Thomas,a   Frédéric Lefebvre,*a   Alexandre Goguet,b   Jacinto Sáb  and  Christopher Hardacre*b  
Author affiliations

* Corresponding authors

a Laboratoire C2P2 (UMR 5265), Equipe LCOMS, ESCPE Lyon, 43 Bd du 11 Novembre 1918, Villeurbanne, Cédex, France
E-mail: lefebvre@cpe.fr

b CenTACat, School of Chemistry and Chemical Engineering, Queen's University, Stranmillis Road, Belfast, Northern Ireland, UK
E-mail: c.hardacre@qub.ac.uk

Abstract

Dodecatungsto-silicic H4SiW12O40 and -phosphoric acids H3PW12O40 were deposited on silica by a classical impregnation technique. The resulting materials were studied by in situ Raman and infrared spectroscopy, XPS and by solid-state 1H MAS NMR as a function of their dehydroxylation temperature. The data show that in the case of H3PW12O40 three silanol groups are protonated while in the case of H4SiW12O40 at least one acidic proton remains. Upon heating this proton reacts leading to a disordered structure and a broadening of the W–O Raman bands.

Graphical abstract: Characterization of silica-supported dodecatungstic heteropolyacids as a function of their dehydroxylation temperature

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Publication details

The article was received on 25 Sep 2008, accepted on 24 Dec 2008 and first published on 04 Feb 2009


Article type: Paper
DOI: 10.1039/B816806G
Dalton Trans., 2009, 2235-2240

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    Characterization of silica-supported dodecatungstic heteropolyacids as a function of their dehydroxylation temperature

    N. Legagneux, J. Basset, A. Thomas, F. Lefebvre, A. Goguet, J. Sá and C. Hardacre, Dalton Trans., 2009, 2235
    DOI: 10.1039/B816806G

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