Issue 9, 2009
From the journal:

Chemical Society Reviews

Main-group and transition-metal complexes of bis(phosphinimino)methanides

Tarun K. Panda*a  and  Peter W. Roesky*b  

* Corresponding authors

a Department of Chemistry, Graduate School of Engineering Science, Osaka University, Japan

b Institut für Anorganische Chemie, Universität Karlsruhe (TH), Karlsruhe, Germany
E-mail: roesky@chemie.uni-karlsruhe.de
Fax: +49 (0)721/6084854
Tel: +49 (0)721/6086117

Abstract

Bis(phosphinimino)methanides exhibit a wide variety of coordination chemistry with almost all elements in the periodic table. This critical review deals with the chemistry and coordination behavior of bulky monoanionic {CH(PPh2NR)2}− bis(phosphinimino)methanide and dianionic {C(PPh2NR)2}2− bis(phosphinimino)methanediide (R = SiMe3, aryl) ligands focusing on s- and p-block as well as transition metals (109 references).

Graphical abstract: Main-group and transition-metal complexes of bis(phosphinimino)methanides

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Article information

DOI
https://doi.org/10.1039/B903651B
Article type
Critical Review
Submitted
23 Feb 2009
First published
02 Jul 2009

Chem. Soc. Rev., 2009,38, 2782-2804

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Main-group and transition-metal complexes of bis(phosphinimino)methanides

T. K. Panda and P. W. Roesky, Chem. Soc. Rev., 2009, 38, 2782 DOI: 10.1039/B903651B

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