Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 21, 2009
Previous Article Next Article

Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!

Author affiliations

Abstract

Silver hexynyl cluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).

Graphical abstract: Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!

Back to tab navigation

Supplementary files

Article information


Submitted
06 Mar 2009
Accepted
12 Mar 2009
First published
01 Apr 2009

Phys. Chem. Chem. Phys., 2009,11, 4132-4135
Article type
Communication

Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!

F. Q. Wang, G. N. Khairallah, G. A. Koutsantonis, C. M. Williams, D. L. Callahan and R. A. J. O’Hair, Phys. Chem. Chem. Phys., 2009, 11, 4132
DOI: 10.1039/B904687A

Social activity

Search articles by author

Spotlight

Advertisements