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Issue 9, 2009
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Trapping in situ scission products of C–O ester bonds by unique coordination supramolecular architectures

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Abstract

Various decomposition products of C–O ether bond cleavage have been trapped in supramolecular architectures as templates based on hydrothermal reaction of three-component metal–carboxylate–phen, which not only results in the formation of [5]pseudorotaxane structure, 3D porous framework and supramolecular structure, but also provides directly crystallographic evidence to explain how the C–O ether bond breaks during decomposition.

Graphical abstract: Trapping in situ scission products of C–O ester bonds by unique coordination supramolecular architectures

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Article information


Submitted
03 Mar 2009
Accepted
18 May 2009
First published
02 Jun 2009

CrystEngComm, 2009,11, 1815-1818
Article type
Communication

Trapping in situ scission products of C–O ester bonds by unique coordination supramolecular architectures

X. Cao, Y. Yao, Y. Qin, Q. Lin, Z. Li, J. Cheng and R. Zhang, CrystEngComm, 2009, 11, 1815
DOI: 10.1039/B904387J

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