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Issue 6, 2009
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The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd3(H2O)9Bi2W22O76]8−

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Abstract

The palladium(II) decorated tungstobismuthate(III) [Pd3 (H2O)9Bi2W22O76]8− (1) has been prepared by a simple one-pot reaction of PdCl2 with Na12[Bi2W22O74(OH)2] in aqueous acidic medium at pH 4.8. Polyanion 1 represents a rare example of a structurally characterized palladium-containing polyoxometalate.

Graphical abstract: The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd3(H2O)9Bi2W22O76]8−

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Supplementary files

Article information


Submitted
21 Nov 2008
Accepted
30 Jan 2009
First published
26 Feb 2009

CrystEngComm, 2009,11, 965-966
Article type
Communication

The palladium(II)-decorated 22-tungsto-2-bismuthate(III), [Pd3(H2O)9Bi2W22O76]8−

L. Bi, M. H. Dickman and U. Kortz, CrystEngComm, 2009, 11, 965
DOI: 10.1039/B820888C

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