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Issue 4, 2009
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Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids :  formation of a cyclotetrameric chiral square

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Abstract

A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)−1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D4 symmetry, its potential as an enantiomer separator was examined.

Graphical abstract: Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids :  formation of a cyclotetrameric chiral square

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Article information


Submitted
05 Nov 2008
Accepted
08 Jan 2009
First published
07 Feb 2009

CrystEngComm, 2009,11, 549-552
Article type
Communication

Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids :  formation of a cyclotetrameric chiral square

K. S. Jeong, B. Lee, J. Kim and N. Jeong, CrystEngComm, 2009, 11, 549
DOI: 10.1039/B819756C

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