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Issue 45, 2009
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Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2]

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Abstract

Photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2] to the platinum σ-alkynyl complex [Cl(PMe3)2Pt–C[triple bond, length as m-dash]CPh] gave facile access to the first transition metal–borirene complex. The title compound has been fully characterized in solution and by X-ray crystallography.

Graphical abstract: Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr [[double bond, length as m-dash]] BN(SiMe3)2]

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Publication details

The article was received on 04 Aug 2009, accepted on 05 Oct 2009 and first published on 15 Oct 2009


Article type: Communication
DOI: 10.1039/B915926F
Chem. Commun., 2009, 6979-6981

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    Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr[double bond, length as m-dash]BN(SiMe3)2]

    H. Braunschweig, Q. Ye and K. Radacki, Chem. Commun., 2009, 6979
    DOI: 10.1039/B915926F

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