Issue 47, 2009
From the journal:

Chemical Communications

Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium†

William J. Evans,*a   Justin R. Walenskya  and  Joseph W. Zillera  

* Corresponding authors

a Department of Chemistry, University of California, Irvine, USA
E-mail: wevans@uci.edu
Fax: +1-949-824-2210

Abstract

A uranium complex containing an outer sphere aryloxide anion is formed by the proteolytic cleavage of the methyl group in the mono-methyl uranium metallocene, (C5Me5)2[iPrNC(Me)NiPr]UMe, by 2,6-di-tert-butyl-4-methyl phenol.

Graphical abstract: Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

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Article information

DOI
https://doi.org/10.1039/B912222B
Article type
Communication
Submitted
22 Jun 2009
Accepted
20 Oct 2009
First published
05 Nov 2009

Chem. Commun., 2009, 7342-7344

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Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

W. J. Evans, J. R. Walensky and J. W. Ziller, Chem. Commun., 2009, 7342 DOI: 10.1039/B912222B

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