Issue 34, 2009

Spirocyclic boronium ions: precursors to persistent neutral radicals

Abstract

Spirocyclic boronium ions based on the 9-bora-9,10-dihydroanthracene scaffold and substituted 2,2′-bipyridyl ligands have been prepared; these cations are shown to be convenient starting materials for the preparation of neutral radicals with significant spin density on boron.

Graphical abstract: Spirocyclic boronium ions: precursors to persistent neutral radicals

Supplementary files

Article information

Article type
Communication
Submitted
19 Jun 2009
Accepted
02 Jul 2009
First published
20 Jul 2009

Chem. Commun., 2009, 5147-5149

Spirocyclic boronium ions: precursors to persistent neutral radicals

T. K. Wood, W. E. Piers, B. A. Keay and M. Parvez, Chem. Commun., 2009, 5147 DOI: 10.1039/B911982E

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