LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT4+ in water

Julien Bigot; Marc Bria; Stuart T. Caldwell; Frédéric Cazaux; Alan Cooper; Bernadette Charleux; Graeme Cooke; Brian Fitzpatrick; David Fournier; Joel Lyskawa; Margaret Nutley; François Stoffelbach; Patrice Woisel

doi:10.1039/B910856D

LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT⁴⁺ in water†

Julien Bigot,^a Marc Bria,^a Stuart T. Caldwell,^b Frédéric Cazaux,^a Alan Cooper,^b Bernadette Charleux,^c Graeme Cooke,*^b Brian Fitzpatrick,^b David Fournier,^a Joel Lyskawa,^a Margaret Nutley,^b François Stoffelbach^c and Patrice Woisel*^a

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* Corresponding authors

^a Laboratoire de Chimie Organique et Macromoléculaire & CCM-RMN Lille 1, Université des Sciences et Technologies de Lille, Villeneuve d’Ascq, France
E-mail: patrice.woisel@ensc-lille.fr

^b WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK
E-mail: graemec@chem.gla.ac.uk

^c Laboratoire de Chimie Macromoléculaire, UMR 7610, 4, place Jussieu, case 185, Tour 44, 1er étage, 75252 Paris cedex 05, France

Abstract

We describe the application of the LCST of a naphthalene-functionalised polyNIPAM derivative as a convenient, tuneable and reversible method to disrupt complex formation with CBPQT⁴⁺ in water.

Chemical Communications

LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT⁴⁺ in water†

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LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT⁴⁺ in water

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