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Issue 30, 2009
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Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds

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Abstract

The phosphanylidene-σ4-phosphorane reagents Me3P[double bond, length as m-dash]PAr (Ar = 2,4,6-tBu3C6H2 and 2,6-Mes2C6H3) are good delivery vehicles of the terminal phosphinidene moiety, PAr, to early-transition metals composed of zirconium and vanadium.

Graphical abstract: Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds

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Publication details

The article was received on 27 May 2009, accepted on 15 Jun 2009 and first published on 06 Jul 2009


Article type: Communication
DOI: 10.1039/B910410K
Chem. Commun., 2009, 4521-4523

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    Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds

    U. J. Kilgore, H. Fan, M. Pink, E. Urnezius, J. D. Protasiewicz and D. J. Mindiola, Chem. Commun., 2009, 4521
    DOI: 10.1039/B910410K

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