Issue 25, 2009

Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

Abstract

In H2O–CHCl3, the phosphonium borane [ortho-(Mes2B)C6H4(PMePh2)]+ selectively complexes azide anions to afford ortho-(Mes2(N3)B)C6H4(PMePh2) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.

Graphical abstract: Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

Supplementary files

Article information

Article type
Communication
Submitted
16 Mar 2009
Accepted
06 May 2009
First published
27 May 2009

Chem. Commun., 2009, 3729-3731

Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

Y. Kim, T. W. Hudnall, G. Bouhadir, D. Bourissou and F. P. Gabbaï, Chem. Commun., 2009, 3729 DOI: 10.1039/B905232A

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