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Issue 23, 2009
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Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

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Abstract

A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)2(tcpd)] (1) (tcpd2− = (C[C(CN)2]3)2−, abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.

Graphical abstract: Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

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Article information


Submitted
03 Feb 2009
Accepted
27 Mar 2009
First published
29 Apr 2009

Chem. Commun., 2009, 3404-3406
Article type
Communication

Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

G. Dupouy, M. Marchivie, S. Triki, J. Sala-Pala, C. J. Gómez-García, S. Pillet, C. Lecomte and J. Létard, Chem. Commun., 2009, 3404
DOI: 10.1039/B902339A

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