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Issue 18, 2009
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A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

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Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Graphical abstract: A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

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Article information


Submitted
17 Dec 2008
Accepted
19 Feb 2009
First published
16 Mar 2009

Chem. Commun., 2009, 2538-2540
Article type
Communication

A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

N. Tsoureas, M. F. Haddow, A. Hamilton and G. R. Owen, Chem. Commun., 2009, 2538
DOI: 10.1039/B822678D

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