Issue 18, 2009
From the journal:

Chemical Communications

A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide†

Nikolaos Tsoureas,a   Mairi F. Haddow,a   Alex Hamiltona  and  Gareth R. Owen‡*a  

* Corresponding authors

a The School of Chemistry, University of Bristol, Bristol, UK
E-mail: gareth.owen@bristol.ac.uk
Fax: +44 (0)117 925 1295
Tel: +44 (0)117 928 7652

Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)3}−] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Graphical abstract: A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

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Article information

DOI
https://doi.org/10.1039/B822678D
Article type
Communication
Submitted
17 Dec 2008
Accepted
19 Feb 2009
First published
16 Mar 2009

Chem. Commun., 2009, 2538-2540

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A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

N. Tsoureas, M. F. Haddow, A. Hamilton and G. R. Owen, Chem. Commun., 2009, 2538 DOI: 10.1039/B822678D

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