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Issue 12, 2009
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First total synthesis of the whole series of the antiostatins A and B

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Abstract

The first synthesis of the whole antiostatin family is described by using an iron-mediated carbazole synthesis, regioselective nitration at C-4 and establishing 5-isobutyl-1-nitrobiuret as a reagent for introduction of the antiostatin B side chain at C-4.

Graphical abstract: First total synthesis of the whole series of the antiostatins A and B

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Article information


Submitted
25 Nov 2008
Accepted
19 Dec 2008
First published
20 Jan 2009

Chem. Commun., 2009, 1467-1469
Article type
Communication

First total synthesis of the whole series of the antiostatins A and B

K. E. Knott, S. Auschill, A. Jäger and H. Knölker, Chem. Commun., 2009, 1467
DOI: 10.1039/B821039J

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