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Issue 17, 2009
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Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process

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Abstract

A racemic bis(nitrile) ligand based on the Tröger’s base scaffold self-assembles into an achiral dinuclear heterochiral rhomb in a diastereoselective self-discrimination process; this occurs upon coordination to (dppp)Pd(OTf)2 as evidenced by nmr spectroscopy and X-ray crystal structure analysis.

Graphical abstract: Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process

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Article information


Submitted
30 Oct 2008
Accepted
27 Feb 2009
First published
17 Mar 2009

Chem. Commun., 2009, 2320-2322
Article type
Communication

Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating process

T. Weilandt, U. Kiehne, G. Schnakenburg and A. Lützen, Chem. Commun., 2009, 2320
DOI: 10.1039/B819335E

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