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Issue 8, 2009
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Arylstibonic acids [H8(RSb)12O28]; precursors to organometallic isopolyoxostibonates [Na2H9(RSb)12O30], (R = aryl)

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Abstract

Electrospray ionisation mass spectrometry shows that arylstibonic acids, RSbO3H2, give rise to oxo-bridged clusters derived from [H8(RSb)12O28] which act as inorganic crown ligands towards Na+ cations; structure determination of one derivative revealed a cage-like anion [Na2H9(p-O2NC6H4Sb)12O30·4H2O].

Graphical abstract: Arylstibonic acids [H8(RSb)12O28]; precursors to organometallic isopolyoxostibonates [Na2H9(RSb)12O30]−, (R = aryl)

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Supplementary files

Article information


Submitted
15 Sep 2008
Accepted
01 Dec 2008
First published
14 Jan 2009

Chem. Commun., 2009, 923-925
Article type
Communication

Arylstibonic acids [H8(RSb)12O28]; precursors to organometallic isopolyoxostibonates [Na2H9(RSb)12O30], (R = aryl)

C. J. Clark, B. K. Nicholson and C. E. Wright, Chem. Commun., 2009, 923
DOI: 10.1039/B816113E

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