Issue 46, 2009
From the journal:

Chemical Communications

Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids†

Josep Cornella,a   Carolina Sanchez,a   David Banawaa  and  Igor Larrosa*a  

* Corresponding authors

a Queen Mary University of London, School of Biological and Chemical Sciences, Joseph Priestley Building, Mile End Road, London, UK
E-mail: i.larrosa@qmul.ac.uk
Fax: +44 (0)20 7882 7427
Tel: +44 (0)20 7882 8404

Abstract

Catalytic amounts of Ag(I) salts in DMSO have been found to promote the protodecarboxylation of a wide variety of ortho-substituted benzoic acids under mild conditions and in excellent yields, highlighting a possible role for silver in decarboxylative cross-couplings.

Graphical abstract: Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

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Article information

DOI
https://doi.org/10.1039/B916646G
Article type
Communication
Submitted
13 Aug 2009
Accepted
22 Sep 2009
First published
28 Oct 2009

Chem. Commun., 2009, 7176-7178

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Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

J. Cornella, C. Sanchez, D. Banawa and I. Larrosa, Chem. Commun., 2009, 7176 DOI: 10.1039/B916646G

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