Issue 34, 2009
From the journal:

Chemical Communications

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynesvia regioselective C–H bond cleavage†

Tatsuya Fukutani,a   Nobuyoshi Umeda,a   Koji Hirano,a   Tetsuya Satoh*a  and  Masahiro Miura*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: satoh@chem.eng.osaka-u.ac.jp, miura@chem.eng.osaka-u.ac.jp
Fax: +81 66879 7362
Tel: +81 66879 7361

Abstract

The rhodium-catalyzed oxidative coupling of aromatic imines with alkynes effectively proceeds via regioselective C–H bond cleavage to produce indenone imine and isoquinoline derivatives.

Graphical abstract: Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

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Article information

DOI
https://doi.org/10.1039/B910198E
Article type
Communication
Submitted
22 May 2009
Accepted
07 Jul 2009
First published
28 Jul 2009

Chem. Commun., 2009, 5141-5143

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Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

T. Fukutani, N. Umeda, K. Hirano, T. Satoh and M. Miura, Chem. Commun., 2009, 5141 DOI: 10.1039/B910198E

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