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Issue 14, 2009
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Aromatic trifluoromethylation catalytic in copper

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Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Graphical abstract: Aromatic trifluoromethylation catalytic in copper

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Supplementary files

Article information


Submitted
24 Dec 2008
Accepted
30 Jan 2009
First published
23 Feb 2009

Chem. Commun., 2009, 1909-1911
Article type
Communication

Aromatic trifluoromethylation catalytic in copper

M. Oishi, H. Kondo and H. Amii, Chem. Commun., 2009, 1909 DOI: 10.1039/B823249K

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